Trains Running (August Wilson) Essays (595 words) -

Trains Running (August Wilson) Trains Running (August Wilson) P.565 Memphis The owner of the diner is waiting for his chance to go back south, and he knows that they got two trains running every day. Wolf A numbers runner who sometimes uses the diner as his office. Risa The diner's waitress and cook. Holloway A regular who speaks out against the constant oppression of African Americans. Sterling Just released from jail, he needs to find a way to make a living. Hambone A man who stands up for what he believes he deserves. West The only wealthy man on stage owns the funeral home across the street. Two Trains Running, set in 1969, is August Wilson's most contemporary play to date. Like most of his plays, it unfolds in a single location--a diner in Pittsburgh. Memphis, the diner's owner, is struggling to get a fair price from the city which is buying up the entire eighborhood for purposes of urban renewal. Memphis' observation that the neighborhood has been emptied of its commercial and human activities gives an ironic and grim spin to urban renewal in particular and the progress of African Americans general. The play asks the question: In the midst of unemployment, death, and a white power structure allowing few alternative, where do you look for salvation. Do you turn to Christianity, as embodies in the wealthy but deceased Prophet Samuel, or do you return to an older African spirituality embodied by the impossibly aged Aunt Ester? Perhaps salvation lays with Malcolm X and the black power movement, or with Wolf and the numbers game of a white Mafia. A host of tragic figures inhabit the diner. Memphis' struggle with the city is essential to his fate of returning south to get back the land cruel taken from his by white men. Sterling--just out of prison--is stymied in his attempts to, by any means possible, support himself. Risa, the waitress, has scarred her legs in an attempt to escape the prison of physical beauty. Finally, perhaps a symbol of them all, is Hambone. Tens years ago he painted the grocer's fence, but was paid a chicken when he felt he had earned a ham. Every day for ten years he has confronted the grocer, requesting and demanding his ham, until by now the only phrases he utters are I want my ham. and He gonna give me my ham. August Wilson's 1992 play Two Trains Running is, in effect, a kinder, gentler version of Spike Lee's film Do the Right Thing. Both address racial tension between blacks and whites in the inner city and the violence that can accompany it, but in the play, these social ills are heard and not seen. The cast of TheatreWorks' current production creates a well-realized, if insular, environment that allows the audience to connect the characters. Wilson has created a compelling story line for each individual, and the fact that most of the stories have happy endings doesn't seem contrived. On the contrary, their successes are representative of African Americans who broke through the color line during the civil rights movement. Even a character like , the diner owner who treats his lone waitress, Risa , as a personal servant, redeems himself through his fight to get the city to pay him what he wants for his building, which is due to be demolished. Memphis plans to use the money to return to Mississippi and confront the white man who ran him off his land decades ago. Memphis' story is at once heartrending and uplifting, as is Abdul-Rashid's reading of it. Philosophy

Persuasive Speech on Distractive Behavior Essays

Persuasive Speech on Distractive Behavior Essays Persuasive Speech on Distractive Behavior Essay Persuasive Speech on Distractive Behavior Essay Essay Topic: Persuasive Title: Distractive Behavior Specific Purpose: To persuade the audience that distractive behavior while driving a car, which would include eating and taking on a cell phone, is dangerous and we need to learn to stop these activities. I. Introduction A. Attention-Getter: Automobiles have become the backbone of America, using them daily to transport us to and from point A to point B efficiently. B. Establishment of Ethos: I am certain that all of us have driven a car and on more than a few times while driving, you’ve eaten food, talked on cell phones and participated in what I call â€Å"Distractive Behavior. C. Preview of Main Points: My purpose is to show the dangers of participating in â€Å"Distractive Behaviors,† by giving examples and statistics and to hopefully get fellow drivers to reduce or cease these actions that put others in harms way. II. Need A. In today’s modern world, our lives are on a constant move and we have begun to use this time to do basic human needs such as applying makeup, eating and communicating. (Mcleod, Annette) 1. More than 20% of all automobile crashes are caused by driver distraction. Mcleod, Annette) 2. Cell phones are not all to blame. B. The need for change, when it comes to Distractive Behavior is non- Deniable, as it will only get worst as technology progresses. (Mcleod, Annette) III. Satisfaction A. While there are no clear-cut ways to rid the road of these dangerous behaviors, there are methods to deterring someone from participating in them. 1. In Columbus, GA, the local army base (Fort Benning) has banned the use of mobile phones while driving on post. 2. Stiff fines and penalty points towards the driver’s license would also be an incentive to hang up and drive. (Webster, Ben) B. Although it is impossible to completely kill some of these habits, like applying makeup and eating because it would be up to the driver to make the safer choice. IV. Visualization A. Try to visualize a road that is safer due to the fact that drivers are completely aware of surrounding and focusing all their attention the road before them. B. Some towns and states are putting in effect laws, which restrict/ ban cell phones while driving. It would be a dream to see these same laws spread across the country. V. Action A. We have all seen the accidents while driving down a road, but do you ever wonder how and why it happened. You can make a difference! 1. Hang up that cell phone. 2. Drive safer; eat your lunch at the house or in the office, not while driving to and from. B. If the people are not willing to hang up that call or put down that McDonald’s hamburger, laws could be put into effect, which would protect the driver and those around them. . Fines that gradually increase with each incidence can be put into effect. 2. Points on your driver’s license if the driver has broken the laws too many times would be another incentive. Mcleod, Annette. â€Å"Driven to Distraction. † 5 Aug 2007. 4 Nov. 2008 lexisnexis. com/ Webster, Ben. â€Å"Hands-free mobiles â€Å"just as dangerous† LexisNexis. 5 Apr. 2007. 4 Nov. 2008 lexisnexis. com/

Common Lacewings, Family Chrysopidae

Common Lacewings, Family Chrysopidae If youre a gardener, you are probably already familiar with the green lacewings. Members of the family Chrysopidae are beneficial insects whose larvae prey on soft-bodied pests, especially aphids. For this reason, common lacewings are sometimes called aphid lions. Description: The family name Chrysopidae derives from the Greek chrysos, meaning gold, and ops, meaning eye or face. Thats a pretty apt description of the common lacewings, most of which have copper-colored eyes. Lacewings in this group are nearly always green in body and wing color, so you may know them as the green lacewings, another common name. Adult lacewings have lacy wings, as you might have guessed, and they look transparent. If you place a Chrysopid wing under magnification, you should see short hairs along the edges and veins of each wing. Lacewings also have long, filiform antennae, and chewing mouthparts. Lacewing larvae look quite different from the adults. They have elongated, flattened bodies, which resemble tiny alligators. Theyre often brownish in color. Lacewing larvae also have large, sickle-shaped jaws, well designed for catching and devouring prey. Classification: Kingdom – AnimaliaPhylum – ArthropodaClass – InsectaOrder – NeuropteraFamily - Chrysopidae Diet: Lacewing larvae feed on other soft-bodied insects or arachnids, including aphids, mealybugs, mites, and Lepidoptera eggs. As adults, lacewings may consume a more varied diet. Some adults are entirely predaceous, while others supplement their diet with pollen (genus Meleoma) or honeydew (genus Eremochrysa). Life Cycle: Common lacewings undergo complete metamorphosis, with four life stages: egg, larva, pupa, and adult. The life cycle varies in length according to species and environmental conditions. Most adults will live for 4-6 months. Before depositing an egg, the female lacewing produces a long, thin stalk, which she usually attaches to the underside of a leaf. She places an egg at the end of the stalk, so it is suspended from the plant. Some lacewings lay their eggs in groups, creating a small cluster of these filaments on a leaf, while others lay eggs singly. The filament is thought to provide some protection for the eggs, by keeping them out of reach of predators on the leaf surface. Generally, the larval stage may last several weeks, and usually requires three instars. Pupae may develop into adults in the safety of a silken cocoon attached to the underside of a leaf or on a stem, but some species pupate without a case. Common lacewings may overwinter as larvae, pupae, or adults, depending on the species. Some individuals are brown, rather than their usual green color, in the overwintering stage. Special Adaptations and Behaviors: In the larval stage, some species camouflage themselves by covering their bodies with debris (usually carcasses of their prey). Each time it molts, the larva must construct a new debris pile. Some lacewings will release a noxious, foul-smelling substance from a pair of glands on the prothorax when handled. Range and Distribution: Common or green lacewings may be found in grassy or weedy habitats, or on other foliage, worldwide. About 85 species inhabit North America, while over 1,200 species are known globally. Sources: Borror and Delongs Introduction to the Study of Insects, 7th edition, by Charles A. Triplehorn and Norman F. JohnsonChrysopidae, University of California-Riverside, accessed December 7, 2012Family Chrysopidae - Green Lacewings, Bugguide.net, accessed December 7, 2012

Control & Co-ordination Assignment Example | Topics and Well Written Essays - 1750 words

Control & Co-ordination - Assignment Example The central nervous system gathers information from the peripheral nervous system and analyzes it to create action, and later resends it to the peripheral nervous system. The central nervous system is made up of the brain and the spinal cord. These two divisions work together to ensure that the body is able to respond to different internal and external changes and environments. A simplified chart showing the organisation of the nervous system is as shown below (Brelt, 2003). The forebrain is responsible for receiving and processing of detailed and complex sensory information, thought, perceptions and language. The forebrain is the part of the brain that differentiates the human beings from other organisms. This part of the brain is comprised of the thalamus and the hypothalamus, the cerebrum and cerebral cortex. The thalamus is responsible for sorting and differentiating information and sending/relaying it to the different parts of the fore brain. The hypothalamus controls and monitors activities such as eating, drinking or sexual activity by affecting the endocrine system to produce hormones. The cerebrum forms the largest part of the forebrain and processes information, relaying it to the cerebral cortex. The cerebral cortex is responsible for speech, grammar, mathematical abilities, non verbal emotions among others (Brelt, 2003). The midbrain is a link between the hind and fore parts of the brain. It relays information between the two brain parts and is responsible with auditory and visual responses such as hearing, sight, and sleep among others. This part of the brain, located just below the cerebral cortex is the smallest as compared to the forebrain and the hindbrain. The hindbrain is located at the rear of the skull and is comprised of the medulla oblongata, the cerebellum and the pons. The medulla oblongata controls activities such as breathing and posture whereas the

Murder of Santiago Nasar in Gabriel Garcia Marquez's Chronicle of a Essay

Murder of Santiago Nasar in Gabriel Garcia Marquez's Chronicle of a Death Foretold - Essay Example Since Santiago was responsible for Angela’s loss of virginity, his death would be expected to be caused by a member or members of the Vicario family; more precisely, Santiago Nasar was killed by two brothers, Pablo and Pedro, from the Vicario family.  Santiago Nasar was going to be killed according to Marquez (67). The two brothers from the Vicario family had vowed to avenge their sister’s virginity since it robbed their family of honor. A bishop’s visit to the town threw the events of the day into disarray and shifted the attention from the foretold murder. The bishop decided, at the last minute, to stay on the boat on which he had travelled rather than get in town. Santiago Nasar was a member of the ruling class, together with his friends’ family. The family of the narrator in the story was close friends with Santiago’s family, which gave the narrator the expectation that before the bishop left the town; he would have personally paid them a visi t. Everyone, for sometime forgets about the saga that involved the return of Angela to her home after the wedding. The Vicario brothers were going to kill Santiago. Except few people, almost all the dwellers of the town including the priest and the mayor were aware that two identical twin brothers, Pablo and Pedro Vicario, were in a mission to find Santiago Nasar with the intention of killing him (Marquez 163). Santiago Nasar remained unaware of the plot by Vicario brothers to kill him until the time they accosted and attacked him. The manner in which the story unfolds is inverted, hence does not give very clear evidence of the murder at first. The story unfolds backwards rather than forwards. The possible reasons for the murder, the circumstances surrounding the murder and the motivation behind it are traced. The evidence that the Vicario brothers were going to kill Santiago is built from the importance they give to accomplishing their revenge mission. Angela Vicario was married by Bayardo San Roman in a flamboyant wedding ceremony. Barely five hours later, Bayardo returned her to her parents. The consequences of not being a virgin were potentially dangerous, a fact that Angela was very much aware. She, in fact, wanted to stop the marriage knowing very well that there existed no love between them. The Vicarious family, were so much impressed by Bayardo’s wealth and were, therefore, opposed to the decision by their daughter to stop the marriage. Her brothers were particularly not pleased by the incident and had vowed to kill whoever had deflowered their sister. Bayardo did not love Angela and neither did she love him. Rather, Bayardo was excited about the idea of marrying a beautiful woman. Bayardo San Roman used the wedding ceremony as an excuse to show off the power and wealth he wielded. According to the narrator’s comment, Bayardo San Roman could marry any woman he wanted to. His wealth and power came from the fact that he had been born of a decorated hero, the only one to defeat Colonel Aureliano Buendia, in a civil war fought in the nineteenth century. Lack of love may not have been a reason good enough to stop the marriage between Angela Vicario and Bayardo San Roman. However, the fact that Angela had lost her virginity to somebody other than her proud husband, Bayardo, was a reason enough to make her return to

Cost Effectiveness Analysis of Bleach

Cost Effectiveness Analysis of Bleach Household bleach is a common commodity used by all income groups of India. This is mainly because of hot and humid climatic condition which left us with no other choice than white or light colour daily wear clothes. To maintain personal hygiene and attractive look within the available budget it is necessary to use bleaches. One question which bothered me quite often was, when so many bleach brands are accessible, which one is the best to buy and this gave me the idea to frame my research question Investigating the cost-effectiveness of various brands of chlorine-based bleaches containing sodium hypochlorite accessible in Indian Market Thus to determine the usefulness and effectiveness of the bleaches, it was worth calculating the concentration of free chlorine per rupee (Indian currency) spent. The different bleaches were selected and the concentration of the free chlorine was calculated using iodometric titration. The cost per rupee was calculated and comparison was done using statistical tools. After necessary calculations and comparison, it was concluded that the most cost-effective bleach is local bleach. Local bleach has maximum concentration of free chlorine per rupee spent. Although the moles of free chlorine in local bleach is just 0.276mol/dm3 while in that of rin and robin are 0.68mol/dm3 and 0.588mol/dm3 respectively. But the local bleach is quite cheaper to other bleaches. It costs 30 rupees/dm3 while Robin costs 66 rupees/dm3 and Rin costs 80 rupees/dm3. The concentration of free chlorine per rupee spent on bleach is 0.0092mol/dm3 while that of Rin bleach and Robin bleach is 0.0085mol/dm3 and 0.0089mol/dm3. Thus, I conclude that Local Bleach brand is the most cost-effective brand among the three available in India. INTRODUCTION: 1.1 Background As climate of India is hot and humid, people prefer to dress in light or white colour cloth. To keep them clean is a necessity for hygiene. Hence it requires daily washing and using bleach as the light colour fabric expose the stains more easily. When used in approved quantity and right way, bleach removes the nasty stains from white color fabric and brings back the brightness. Looking into Indian economy, it is not possible to buy dresses in large number by masses . Thus easy way out is the use of bleaches. So when I started looking for a topic for my extended essay, my intensions were very clear. I was looking for an area for investigation which will help me to fulfill my requirement to do an essay for my diploma and give me the dual benefit to help my countrymen to choose a better and cost effective bleach which is affordable by them. I have collected the three bleaches which were having the maximum sale in the market , two were branded viz., Rin and Robin and one was a local brand usually purchased by lower income group people. Bleach is a chemical that removes colors or whitens, often via oxidation. Common chemical bleaches include household chlorine bleach, a solution of approximately 3-6% sodium hypochlorite (NaClO), and oxygen bleach, which contains hydrogen peroxide or a peroxide-releasing compound such as sodium perborate, sodium percarbonate, sodium persulfate, tetrasodium pyrophosphate, or urea peroxide together with catalysts and activators, e.g., tetraacetylethylenediamine and/or sodium nonanoyloxybenzenesulfonate.[1] There are other types of bleaches as well for example bleaches which hare used for the bleaching of wood pulp, fats and oils, cellulose, flour, textiles, bee wax, skin etc. the commonly used bleach for this purpose is chlorine dioxide and in a number of other industries. In the food industry, some organic peroxides(benzoyl peroxide,etc.) and other agents (e.g., bromates) are used as flour bleaching and maturing agents. Peracetic acid and ozone are used in the manufacture of paper products, especially newsprint and white Kraft paper.[2] But my investigation is related to household bleach used for removal of stains , which usually contain chlorine, though it often masquerades behind aliases such as sodium hypochlorite or hypochlorite.[3] Household bleach, used to whiten fabrics or remove mold from surfaces, is a 5% solution of a stabilized form of chlorine.[4] It is particularly effective on cotton fiber, which stains easily but bleaches well. Usually 50 to 250 ml of bleach per load is recommended for a standard-size washer. The properties of household bleach that make it effective for removing stains also result in cumulative damage to organic fibers such as cotton, and the useful lifespan of these materials will be shortened with regular bleaching. The sodium hydroxide (NaOH) that is also found in household bleach (as noted later) causes fiber degradation as well. It is not volatile, and residual amounts of NaOH not rinsed out will continue slowly degrading organic fibers in the presence of humidity. For these reasons, if stains are localized, spot treatments should be considered whenever possible. With safety precautions, post-treatment with weak organic acids such as acetic acid (vinegar) will neutralize the NaOH, and volatilize the chlorine from residual hypochlorite. Old t-shirts and cotton sheets that rip easily demonstrate the cost s of laundering with household bleach. Hot water increases the activity of the bleach, owing to the thermal decomposition of hypochlorite which ultimately generates environmentally-undesirable chlorate.[5] Color in most dyes and pigments are produced by molecules, such as beta carotene, which contain chromophores. Chemical bleaches work in one of two ways: An oxidizing bleach works by breaking the chemical bonds that make up the chromophore. This changes the molecule into a different substance that either does not contain a chromophore, or contains a chromophore that does not absorb visible light. Reducing bleach works by converting double bonds in the chromophore into single bonds. This eliminates the ability of the chromophore to absorb visible light.[6] The chlorine based bleaches are oxidized bleach. These bleaches have an edge over reducing bleaches because they act as disinfectant as well. The process of bleaching can be summarized in the following set of chemical reactions: Cl2(aq) + H2O(l) H+(aq) + Cl-(aq) + HClO(aq) The H+ ion of the hypochlorous acid then dissolves into solution, and so the final result is effectively: Cl2 (aq) + H2O (l) 2H+ (aq) + Cl-(aq) + ClO-(aq) Hypochlorite tends to decompose into chloride and a highly reactive form of oxygen: ClO- Cl- +1/2 O2 This oxygen then reacts with organic substances to produce bleaching or antiseptic effects.[7] To begin my investigation I gathered information about brands of chlorine based bleach, its uses and its contents. From the information collected I found out that sodium hypochlorite is an active ingredient in bleaches. Sodium hypochlorite is the magical ingredient which removes stains from the clothes. So if I find out which bleach has the more concentration of sodium hypochlorite and is cheaper than other bleaches will be considered as the best bleach for Indian people. This observation led to my precise topic selection that is Investigating the cost-effectiveness of various brands of chlorine-based bleaches containing sodium hypochlorite accessible in Indian Market After selection of topic next obvious step was to find various methods available in literature and select for an appropriate method for the estimation of the sodium hypochlorite in the bleaches. Various methods available are discussed in the methodology section of my essay. The one I have selected is based on the fact that it is easy to do and also gives a fair estimation of the concentration of hypochlorite in the available laboratory conditions. 1.2 Methods to judge the cost effectiveness of Bleach Some of the methods available in literature for the estimation of concentration of sodium hypochlorite are discussed below: Method 1: One of the common methods is to add excess hydrogen peroxide to a measured amount of bleach. This will result in the formation of oxygen gas. The volume of the gas is collected over water and measured. This is then used to calculate the concentration of sodium hypochlorite in a house hold bleach sample. A few commercial bleaches in their containers, with prices, can be placed on a suitable tray, each with a 10 cm3 syringe and 250 cm3 beaker, both labeled, into which small samples of the bleach can be placed. Measure 5 cm3 of each bleach into their side-arm flask for each experiment. Small samples of the hydrogen peroxide solution could be collected in a 100 cm3 beaker. Bleaches liberate toxic chlorine gas on contact with acids. The chemical reaction involved is H2O2(aq) + NaOCl(aq) à ¢Ã¢â‚¬  Ã¢â‚¬â„¢ H2O(l) + NaCl(aq) + O2(g) Direct comparison of volume of oxygen collected in the measuring cylinder can be used to compare the effectiveness of the bleach.[8] Method 2: Spectophotometric method has also been employed for the quantitative estimation of sodium hypochlorite in commercially available bleach solution. The method is based directly on the absorbance of hypochlorite in alkaline aqueous media. The other method takes advantage of the quantitative reaction of hypochlorite and ammonia in alkaline solution to form chloramine, which has a higher molar absorptivity.[9] Method 3: Another most common laboratory method is IODOMETRIC TITRATION. We can determine the OCl- ion content of a bleaching solution by reacting a known mass or volume of the solution with excess reducing agent, such as iodide ion (I-) in an acidic solution. OCl- (aq, colorless) + 2I-(aq, colorless) + 2H3O+(aq) -> I2(aq, brown) + Cl-(aq, colorless) + 3H2O(l) The reaction above proceeds to completion. Visible evidence of reaction is the change in the appearance of the solution from colorless to brown, due to the formation of iodine (I2). In the presence of excess I- ion, the amount of I2 formed is a measure of the amount of OCl- ion reacting. Then we determine the amount of I2 formed by titrating the I2 with a standard sodium thiosulfate solution (Na2S2O3). The titration reaction for this experiment is shown in the equation below. I2 (aq, brown) + 2 S2O3-2(aq, colorless) > 2I ­- + 2S4O3-2(aq, colorless) Thiosulfate ion is a reducing agent that reacts quantitatively with I2. The titration reaction is complete when the I2 formed from the reaction of OCl ­Ãƒâ€šÃ‚ ­- ion with I ­- ion is reconverted to I- ion by S2O3-2 ion. As the titration proceeds, the I2 concentration in the solution decreases. This causes the solution color to change from brown to pale yellow near the end of titration. The end point occurs when all the I2 has reacted and the solution is colorless. Because the change from yellow to colorless is not very distinct, establishing the end point of this final color change is difficult. We can make the end point more distinct by adding a small amount of starch solution to the titration mixture when the solution turns pale yellow. The unreacted I2 combines with the starch, forming a deep blue complex. The starch molecules tend to curl up into spirals and the hole formed is just the right size for the iodine molecules to fit in. Additional S2O3-2 ion reacts with the complex I2, causing a breakdown of the complex. Disappearance of the blue color signals the end point.[10] We can determine the concentration of OCl- ion in the solution. The moles of iodine in the solution are equal to moles of sodium hypochlorite. So then we can find out the concentration of OCl-. I have used the iodometric titration for my investigation because It is easy to carry it out in school laboratory conditions. Gas volume measurement often leads to more random errors in the measurements which ultimately affect the concentration calculations. Spectrophotometric methods are most reliable method but due to non availability of the instrument, I took the decision to stick to iodometric titration. 2. METHODOLOGY: 2.1 Hypothesis More the sodium thiosulfate used to titrate the solution more effective is the bleach at removing the stains. The bleach which has high concentration of sodium hypochlorite is better at removing stains then the bleach with less concentration of sodium hypochlorite. Based on Indian mentality, the expensive the bleach the better is it at removing the stains. The expensive brand should be more cost effective. 2.2 Selection of bleaches 3 different chlorine-based bleaches containing sodium hypochlorite which are easily available in Indian market. The first one is rin bleach which is thought to be the best bleach because it is expensive of all bleaches available in the market. It costs 40 Rs for 500 ml. The second bleach which I have taken is robin which costs 33 Rs for 500ml, a great competitor to RIN. And the third bleach which I have taken is bleach from a local brand which costs only 15Rs for 500ml. 2.3 Experiment 1 Make a soya bean solution using 17 grams of soyabean and dissolved up to 100 cm3 mark. Put three drops of the solution on a piece of cloth and using a syringe the amount of bleach required to remove the stain should be noted down. 2.4 Experiment 2 As told earlier I will be using titration with sodium thiosulfate for calculating the concentration of sodium thiosulfate in the bleaches. The method involves two main steps. Step 1: Standardizing the solution of sodium thiosulfate solution As sodium thiosulfate is not a primary standard, so it was standardized using a known concentration of potassium iodate KIO3 and the exact concentration of sodium thiosulfate was calculated. Approximately 8.00 ±0.01 grams of sodium thiosulfate (Na2S2O3 5H2O) was taken a 100 cm3 beaker and dissolved by adding small amount of double distilled water. It was stirred using a glass rod till it was completely dissolved. Solution was transferred to 250 cm3 of standard flask carefully using a funnel. Solution was made up to the mark and mixed well by tilting the flask three times. A solution of potassium iodate, KIO3 (0.2 Mole/dm3) was prepared by dissolving 10.7 ±0.01 grams of KIO3 in 100 cm3 beaker and dissolving it in minimum amount of water and making the solution in 250 cm3 standard flask. Further 25.0 ±0.06 cm3 of KIO3 solution is pipette out using a 25.0 ±0.06 cm3 pipette and a pipette filler and poured in standard measuring flask and solution was made 250 cm3 using distilled water. Preparation of 1 mol/dm3 of sulfuric acid Take 55cm3 of 98% pure sulphuric acid in 100cm3 measuring flask. Now slowly pour this acid into 500cm3 of constantly stirred water in a beaker Now transfer this solution into 1dm3 conical flask and add water till the 1dm3 mark. Preparation of 10% potassium iodide Take 10grams of potassium iodide Dissolve it in 100cm3 solution Preparation of 2%starch indicator Take 2grams of starch Add little bit of cold water until a smooth paste is obtained Add 100cm3 of boiling water and stir Heat the solution until the solution is clear 25.0 ±0.06 cm3 of KIO3 solution is pipette out using a 25.0 ±0.06 cm3 pipette and a pipette filler and poured in conical flask. 10.00 ±0.05 cm3 of potassium iodide (10% w/v) is added to the flask using a measuring cylinder. To this solution 10 .00 ±0.05 cm3 of sulfuric acid (1 mol/dm3) is added to the flask using another measuring cylinder. Sodium thiosulfate is filled in 50.00 ±0.05 cm3 burette and added to the conical flask containing KIO3, KI and H2SO4solution till the solution in the conical flask turned pale yellow. 2 to 3 drops of starch solution (1% w/v) was added to the conical flask. The solution turned blue black. More sodium thiosulfate was added to the conical flask with constant swirling till the solution turned colorless. The final volume of thiosulfate solution added is recorded Three concordant readings are taken to have consistency in the recorded data Step 2: Titration of the different brands of bleaches using standardized solution of sodium thiosulfate. Thus calculating the concentration of sodium hypochlorite present in different brands of bleaches. Procedure: I have taken 25.0 ±0.06cm3 of Rin bleach using a pipette and pipette filler into 250cm3 graduated flask. To this water was added to make the solution up to 250cm3 mark. 25.0 ±0.06cm3 of the solution poured with the help of pipette into a conical flask and the same procedure as given above was repeated with RIN bleach followed by the other two bleaches, Robin and local brand. 3. Data collection and processing: 3.1 Finding out the concentration of Sodium Thiosulfate Standardization of sodium thiosulfate: Volume of potassium iodate taken in conical flask = 25.0 ±0.06 cm3 final burette reading / cm3 ±0.05cm3 20.10 19.90 20.00 initial burette reading / cm3 ±0.05cm3 0.00 0.00 0.00 volume of sodium thiosulfate used / cm3 ±0.1cm3 20.10 19.90 20.00 Average volume of sodium thiosulfate used = 20.00 cm3 Calculations: 25.0 cm3 of KIO3 solution required 20.00 cm3 of Sodium thiosulfate. The ionic equation related to the titration is IO3-1 + 5I-1 + 6H+  ® 3I2 + 3H2O The I2 produced by the reaction between iodate ion and iodide ion is related stoichiometrically to thiosulfate ion as follows I2 + 2S2O32-  ® S4O62- + 2I-1 Moles of KIO3 (0.1 Mol/dm3) in diluted solution = 0.01 mol/dm3 Moles of 0.01 mol/dm3 KIO3 in 25 cm3 of solution = 0.01 x 25 x 10-3 = 0.25 x10-3 Ratio of moles of KIO3: I2 1 : 5 So moles of I2 in solution = 5 x 1 x 0.25 x10-3 = 1.25 x10-3 Ratio of moles of I2 : S2O32- 1 : 2 Therefore moles of thiosulfate = 2 x 1 x 1.25 x10-3 = 2.50 x 10-3 20.00 cm3 of thiosulfate solution has 2.50 x 10-3 moles Therefore the concentration of thiosulfate solution = 2.50 x 10-3 x 103/20.00 = 0.125 mol/dm3 3.2 collection T value for the t- test between RIN and ROBIN is 36.83644 This value is a lot higher than the cut off value (2.31. using degrees of freedom= [n1-1] + [n2-1] = 8) at a 5% significance level. This implies that there is lot lesser than .1% chance that the 2sets of readings belong to one population or the difference is just difference is insignificant. 3.3 Calculation 25.0 cm3 of diluted Rin brand bleach solution required 27.8 cm3 of Sodium thiosulfate. Moles of sodium thiosulphate= Moles of iodine, I2, were present in the conical flask after the bleach reacted with an excess of iodide ions 2S2O32-(aq) + I2(aq) S4O62-(aq) + 2I-(aq) Moles of I2 = moles of sodium thiosulphate à · 2 Moles of I2 = 0.00348 à · 2 Moles of I2 = 0.0017 moles 1 mol of iodine is displaced by 1 mol of free chlorine. Cl 2(aq) + 2I-(aq) 2Cl-(aq) + I2 (aq) The free chlorine concentration, in mol dm-3, of the bleach RIN 1 mole iodine = 1 mole of free chlorine à ¢Ã‹â€ Ã‚ ´25cm3 of diluted bleach solution contains 0.0017 moles of chlorine Therefore the undiluted bleach solution of 25 cm3 would contain .017 moles Concentration of iodine in 500 cm3 of RIN bleach solution is Therefore the concentration is 0.34mol/500cm3 of RIN bleach. Therefore the concentration is 0.68mol/dm3. 25.0 cm3 of diluted Robin brand bleach solution required 23.53 cm3 of Sodium thiosulfate. Moles of sodium thiosulphate= Moles of iodine, I2, were present in the conical flask after the bleach reacted with an excess of iodide ions 2S2O32-(aq) + I2(aq) S4O62-(aq) + 2I-(aq) Moles of I2 = moles of sodium thiosulphate à · 2 Moles of I2 = 0.00294 à · 2 Moles of I2 = 0.00147 moles 1 mol of iodine is displaced by 1 mol of free chlorine. Cl 2(aq) + 2I-(aq) 2Cl-(aq) + I2 (aq) The free chlorine concentration, in mol dm-3, of the bleach RIN 1 mole iodine = 1 mole of free chlorine à ¢Ã‹â€ Ã‚ ´25cm3 of dilute bleach solution contains 0.00147 moles of chlorine Concentration of iodine in 500 cm3 of Robin bleach solution is Therefore the concentration is 0.294 mol/500cm3 of Robin bleach. Therefore the concentration is 0.588mol/dm3. 25.0 cm3 of diluted LOCAL brand bleach solution required 11.07 cm3 of Sodium thiosulfate. Moles of sodium thiosulphate= Moles of iodine, I2, were present in the conical flask after the bleach reacted with an excess of iodide ions 2S2O32-(aq) + I2(aq) S4O62-(aq) + 2I-(aq) Moles of I2 = moles of sodium thiosulphate à · 2 Moles of I2 = à · 2 Moles of I2 = 0.00069 moles 1 mol of iodine is displaced by 1 mol of free chlorine. Cl 2(aq) + 2I-(aq) 2Cl-(aq) + I2 (aq) The free chlorine concentration, in mol dm-3, of the bleach RIN 1 mole iodine = 1 mole of free chlorine à ¢Ã‹â€ Ã‚ ´25cm3 of diluted bleach solution contains 0.00069 moles of chlorine Concentration of iodine in 500 cm3 of Local bleach solution is Therefore the concentration is 0.138mol/500cm3 of RIN bleach. Therefore the concentration is 0.276mol/dm3. 3.4 analysis and interpretation Calculating the cost-effectiveness BRAND RIN ROBIN LOCAL Concentration of free chlorine (mol/dm3) 0.68 0.588 0.276 Price of 500cm3 bleach in rupees 40 33 15 Price of 1dm3 bleach (=price of 500cm3ÃÆ'-2) in rupees 80 66 30 Concentration of free chlorine per rupee spent on bleach (=concentration of free chlorine in 1dm3 bleach/price of 1 dm3 bleach) 0.0085 0.0089 0.0092 Matrix 1 It can be seen from the experiment 1 higher amounts of bleach is used to remove the stain as we move from RIN to ROBIN to the local brand. And as it can also be seen from the histogram above (graph 1) that the free chlorine concentration decreases as we move from RIN to ROBIN to the local brand it can be inferred that higher the concentration lesser is the amount of bleach required. How so ever the amount of free chlorine required is nearly the same 4. Conclusion: 4.1 Results The free chlorine concentration per rupee spent is maximum of local brand bleach. Therefore the local bleach is most cost-effective bleach. The local brand bleach over takes other branded bleaches like RIN and Robin which are very famous in Indian market. There is a very small difference between each of them when we calculate the concentration of free chlorine per rupee spent. But when we see the concentration of free chlorine in rin and robin they are quite higher then local brand. Local brand has very less moles of sodium hypochlorite per dm3 of the bleach. So the volume required to remove a stain by local brand bleach would be quite large then the volume required of rin or robin brand bleach. This can give a wrong impression that the other brands are better or more efficient at removing stain. But we know that it isnt so. Only if higher amounts of the local brands were used the same stain would take lesser money to be removed. This proves the Indian mentality. Resolved questions Is the amount of sodium thiosulfate used proportional to the amount of free chlorine atoms- Yes very much. It can be inferred by comparing graph 1 (or matrix 1) and graph 2 Does the concentration of sodium hypochlorite affect the effectiveness of the bleach- Higher the concentration of sodium hypochlorite more is the effectiveness of the bleach. Inferred from graph 1 (or matrix 1) and table 1 Checking the Indian mentality- It depends on the amount of bleach used. But it can easily be inferred that the local brand is a lot more cost efficient Deriving the cost effectiveness of different brands of bleach Hypothesis 1 and 2 were confirmed to be true via experimentation while the other two hypotheses (namely 3 and 4) are proved to be wrong. Evaluation Weaknesses It isnt very easy to note down the point of the end of the titration. Accuracy can tend to pose a problem The distil water can have other salts present Improvements Colorimetry should be used for knowing the end point More accurate burettes can be used Ultra pure water should be used rather than distilled water 4.2 Extension The other method should be used. A more number of brands should be used. Other active ingredients should be tested for. Biologically active organisms like bacterias should also be considered. The activity of the other active substances should be tested. 5. BIBLOGRAPHY: http://en.wikipedia.org/wiki/Bleach http://www.ozonesolutions.com/Ozone_Color_Removal.html http://www.care2.com/grrenliving/chlorine-in-household-cleaners.html# http://dhs.wi.gov/eh/ChemFS/fs/chlorine.htm http://en.wikipedia.org/wiki/Sodium_hypochlorite Field, Simon Q (2006). Ingredients Bleach. Science Toys. http://sci-toys.com/ingredients/bleach.html. Retrieved 2006-03-02. http://en.wikipedia.org/wiki/Bleach http://www.practicalchemistry.org/experiments/estimation-of-the-concentration-of-household-bleach,253,EX.html Journal of pharmaceutical sciences, volume 59, issue 8, pages 1168, 1170 www.cerlabs.com/experiments/10875404162.pdf Other Sources Referred: Advanced Subsidiary Level and Advanced Level May/June 2006 paper http://science.jrank.org/pages/6243/Sodium-Hypochlorite.html http://www.howstuffworks.com/question189.htm http://www.factsaboutbleach.com/ Handbook of detergents, Volume 5 By Uri Tsoler, Guy Broze. Pages 621-627

An Introduction to Qualitative Analysis Essay

Procedure Part I – Qualitative Analysis of Group 2 Elements Mix 0.02M K2CrO4 with each Mg(NO3)2, Ca(NO3)2, Sr(NO3)2 and Ba(NO3)2 together. Secondly, mix 0.1M (NH4)2C2O4 instead of 0.02M K2CrO4 together with the same reactants used before. Thirdly, mix 0.1M Na2SO4 with those reactants. Then, mix 0.1M NaOH with the same reactants used before again. Some precipitates should forms ,record the observations in Table 1. At last, identify those two unknown solution. Part II- Qualitative Analysis of Selected Anions First mix 1M HNO3 with each Na2CO3, Na2SO4, NaCl and NaI together. Repeat these steps by placing 0.1M Ba(NO3)2 instead of 1M HNO3. Then mix 1M HNO3 for the reactants that formed precipitates. Repeat the first step by placing 0.1M AgNO3 instead of 1M HNO3. Then add 6M NH3 to those mixtures that contains precipitates in, and 1M HNO3 the mixtures contains precipitates . Using these observation, identify an unknown union. Recording all the observations in Table 2. 3. State the identity of your unknown (along with its sample number). Give the reasoning you used to arrive at this conclusion. The Unknown Z should be SO42- because it has a same property as SO42- does. When SO42- is added to Ba(No3)2, and AgNo3, it forms a ppt; for the unknown anion, when it is added to Ba(No3)2, and AgNo3, it forms a ppt as well. When HNO3 is added to BaSO4, the ppt disappeared; for the unknown anion, when HNO3 is added to unknown, the ppt disappeared too, therefore we can conclude that the unknown is SO42-. Follow-Up Questions: 1. Devise a sequence of reactions to follow (using filtering or centrifuging where necessary to remove precipitates) to identify an unknown containing two or more cations of Group 2 elements. The Group 2 elements are Mg, Ca, Sr, and Ba. To identify an unknown containing two or more cations of Group 2 elements, first add CrO4 into the solution. Then we could identify them with their colour. Next we add C2O4, if the ppt is formed, then we know Ca2+ is involved in the solution. Next we add OH into the solution, if a ppt formed, that means Mg2+ is involved in the solution. 2.Devise a sequence of reaction to follow (using filtering or centrifuging where necessary to remove precipitates)to identify an unknown consisting of two or more of two or more of the anions tested in Part 2. The anions are CO32-,SO42-,Cl-,I-.To identify an unknown consisting of two or more anions in Part 2.First add HNO3 into solution. Then we could identify them with the observations. Then we add Ba(NO3)2,if ppt formed, then we know that CO32-is involved in the solution. Next we add HNO3 into the solution, if ppt formed, that means SO42- is involved I the solution. 3. Why are the reagents used to test for cations usually alkali metal salts or ammonium salts rather than salts of other metals? The reagents used to test for cations usually alkali metal salt or ammonium salts rather than salts of other metals because the alkali metal is soluble with most anions. It won’t form a ppt with other anions. These reagents will prevent any side reaction from occurring in the solution. 4. Why are the reagents used to test for anions usually a nitrate of the  cation that is reacting rather than other salts of that cation? The reagents used to test for anions usually a nitrate of the cation that is reacting rather than other salts of that cation because the nitrate is soluble with almost every cation. 5.For fast and accurate identification of substances, major research or testing laboratories now use very sophisticated (and expensive )equipment. Find out the name of one of the instruments now used for analysis, and briefly describe its method of operation. Use glass pane. When we do the lab, we make a table on the paper, then put the glass pane on the paper sheet. After that, we only drop one or two drops of each chemical. On the glass pane. It’s easier to observe the color of ppt because the glass is transparent and it’s also a economic way. Conclusion: In this lab, we carry out precipitation test of four cations and four anions, and use the observations to identify two unknowns. First we mix Mg2+, Ca2+, Sr2+, Ba2+ with K2CrO4, and observed that Sr2+ and Ba2+ forms a ppt. Then when we mix (NH4)2C2O4 instead of K2CrO4, we observed that all of the cations forms a ppt except for Mg2+. Next, we did the same thing by using Na2SO4 and NaOH instead of (NH4)2C2O4 . Lastly, we examined unknown B and found that it has the same chemical properties with Ca2+. So we conclude that the unknown substance should be Ca2+. In part II, we mix CO32-, SO42-, Cl-, and I- with HNO3 to each of the test tube and notice no ppt formed. Secondly, we mix Ba(NO3)2 instead of HNO3 with the anions, and we observed that CO32- and SO42- forms a ppt. Then we add HNO3 to the ones that formed ppt, and the ppt disappeared. Next, we mix AgNO3 instead of Ba(NO3)2 with the anions, and observed ppt formed with all of the anions except for SO42-. After that, we added HNO3 and NH3 separately to the anions and we observed no change in SO42-, but the precipitates that formed in CO32-, Cl-, and I- disappeared. And there is a ppt formed when NH3 is added to SO42-, and the other ones’ precipitates turns to a lighter ppt. By  using these observations, we found out the unknown ion contains the same chemical properties as SO42-. And if two ions are soluble to each other, there will be no ppt formed. If two ions are not soluble to each other, there will be a ppt formed.